Nhiệt Động Học Hóa Học: Phiên Bản Thứ Ba - Tóm Tắt và Nội Dung Chính

Trường đại học

Zuyd University

Người đăng

Ẩn danh

Thể loại

textbook

2010

236
0
0

Phí lưu trữ

55 Point

Mục lục chi tiết

Preface

Preface to the Second Edition

Preface to the First Edition

1. Symbols and Abbreviations

2. The Realm of Thermodynamics

3. Nature’s Driving Forces

4. Setting the Scene: Basic Ideas

4.1. System and Surroundings

4.2. Functions of State

4.3. Mechanical Work and Expanding Gases

4.4. The Absolute Temperature Scale

4.5. Forms of Energy and Their Interconversion

4.6. Forms of Renewable Energy

5. The First Law of Thermodynamics

5.1. Statement of the First Law

5.2. Reversible Expansion of an Ideal Gas

5.3. Constant-Volume Processes

5.4. Constant-Pressure Processes

5.5. A New Function: Enthalpy

5.6. Relationship between ΔH and ΔU

5.7. Uses and Conventions of ΔH

5.8. Enthalpy Change of Reaction

5.9. Standard Enthalpies of Formation

5.10. The Many Uses of Δf H0 Data

6. Chapter 3.2 Differential Scanning Calorimetry

6.1. Concepts of Heat Capacity

6.2. Combustion and Flame Temperatures

6.3. Variation of Reaction Enthalpies with Temperature

6.4. Average Bond Dissociation Energies

6.5. Exothermicity: A Possible Criterion

6.6. Spontaneous Exothermic Processes

6.7. Spontaneous Processes Involving No Heat Change

7. The Second Driving Force

7.1. Measurement of Entropy

7.2. The Second Law of Thermodynamics

7.3. Reversibility and Entropy

7.4. Isothermal Expansion of Gases

7.5. Reversible Transfer of Heat

7.6. An Irreversible Change

7.7. Changes in Entropy with Temperature

7.8. An Adiabatic Compression

8. The Third Law of Thermodynamics

8.1. ΔS for Phase Changes

8.2. The Direction of Time

9. Free Energy: The Arbiter

9.1. Processes in Isolated Systems

9.2. Gibbs Free Energy, G

9.3. Gibbs Free Energy and Maximum Work

9.4. Some Processes in Terms of Gibbs Free Energy

9.5. Endothermic Chemical Processes

9.6. Exothermic Chemical Process

9.7. Standard Free Energy Changes

9.8. Variation of G with Gas Pressure

9.9. Pressure and Chemical Potential for Ideal Gases

9.10. Chemical Potential for Real Gases

9.11. The Active Mass of Pure Liquids and Solids

9.12. Activity of Materials in Solution

9.13. Solutes or Minor Components

9.14. A Summing Up: Activity as a Unifying Concept

9.15. Practical Aspects of Activity

10. Equilibrium and the Reaction Isotherm

10.1. Equilibrium Experiments and Their Interpretation

10.2. The Reaction Isochore Equation

10.3. Le Chatelier Up to Date

10.4. Applications of the Isochore Equation

10.5. The Decomposition of the Compound Fe(OH)3

10.6. The High-Temperature Dissociation of Water Vapor

10.7. The Clapeyron Equation

10.8. Standard Electrode Potentials

10.9. Variation of Cell Electromotive Force with Activity

10.10. Analysis of Electromotive Force Data to Find E 0

10.11. Variation of Electromotive Force with Temperature

11. Free Energy and Industrial Processes

11.1. Free Energies as a Function of Temperature

11.2. The Gibbs-Helmholtz Equation

11.3. The Integrated Form of the Gibbs-Helmholtz Equation

11.4. Tabulated Forms of Free Energy

11.5. The Synthesis of Ethanol

11.6. Use of Activity Coefficients

11.7. Electrolysis of Alumina

11.8. Thermal Reduction of Magnesia

11.9. Titanium and the Kroll Process

11.10. Silicon Metal Production

11.10.1. Calculation of an Adiabatic Flame Temperature

11.10.2. Precipitation of Carbide and Nitride Phases from Dilute Solution in Alloy Steel

11.10.3. CVD Production of Ultrapure Silicon

11.10.4. Processing of Wastes from the Aluminum Electrolytic Furnace

11.10.5. Production of Metallurgical-Grade Silicon in an Arc (Oven) Furnace

Suggested Further Reading

Author

Concise chemical thermodynamics third edition 1