Hóa Học Vật Lý Của Đại Phân Tử: Từ Cơ Bản Đến Ứng Dụng

Trường đại học

Carnegie Mellon University

Chuyên ngành

Hóa học vật lý

Người đăng

Ẩn danh

Thể loại

sách

2007

154
0
0

Phí lưu trữ

45 Point

Mục lục chi tiết

1. CHAPTER ONE: Introduction to macromolecules

1.1. What is a macromolecule?

1.2. The discovery of macromolecules

1.3. The structure of macromolecules in solution

1.4. The remarkable properties of pure bulk polymers

1.5. Building new materials using macromolecules

1.6. Suggestions for further reading

2. CHAPTER TWO: Describing polymer structure

2.1. Geometric structure of macromolecules

2.2. Bond probability distributions

2.3. Rotational isomeric state approximation

2.4. Mean-squared end-to-end distance

2.5. Statistics of the random coil

2.6. Chain flexibility and the persistence length

3. CHAPTER THREE: Measuring polymer structure

3.1. Polymer composition and sequence distribution

3.2. NMR spectroscopy of polymers

3.3. Measuring local conformations of polymers

3.4. Conformational statistics of n-hexane

3.5. Global measures of the chain structure

3.6. Light scattering from dilute polymer solutions

4. CHAPTER FOUR: The macromolecular basis of rubber elasticity

4.1. The thermodynamics of ideal-rubber elasticity

4.2. The statistical theory of rubber elasticity

4.3. Thermoelastic inversion point

4.4. The force of extension of real rubber

5. CHAPTER FIVE: Structure and properties of polymers in dilute solution

5.1. The structure of macromolecules in dilute solution

5.2. Flory theory of chain expansion

5.3. Thermodynamics of two component solutions

5.4. Flory theory of the second virial coefficient

5.5. Light scattering from two-component solutions

5.6. Flory theory of light scattering in dilute solution

5.7. Diffusion of particles in solution

5.8. Kirkwood theory of macromolecular friction

5.9. Concentration fluctuations and mutual diffusion

5.10. The viscosity of dilute polymer solutions

5.11. The effect of molecular-weight polydispersity

6. CHAPTER SIX: Structure and properties of polymers in semidilute solution

6.1. The remarkable behavior of semidilute solutions

6.2. Microscopic theory of semidilute solutions

6.3. Viscosity in semidilute solutions

6.4. Structure near overlap

7. CHAPTER SEVEN: Structure and properties of polymers in concentrated solution

7.1. Flory-Huggins theory of concentrated solutions

7.2. The thermodynamics of swollen rubber: gels

7.3. Light scattering from concentrated solutions

7.4. Real solutions and the Flory–Orwoll theory

7.5. Diffusion in concentrated solutions

7.6. Viscoelasticity in concentrated polymer solutions

8. CHAPTER EIGHT: Structure and properties of polymers in the pure amorphous liquid state

8.1. Free volume and viscosity

8.2. Viscosity of low-molecular-weight chain liquids

8.3. Phenomenology of the glass transition

8.4. Temperature and pressure dependence of relaxation near the glass transition

9. CHAPTER NINE: Structure and properties of rodlike polymers in solution

9.1. Characterization of rodlike polymers in solution

9.2. Second osmotic virial coefficient

9.3. Thermodynamics of rodlike polymer solutions

10. CHAPTER TEN: Structure and properties of polyelectrolyte chains in solution

10.1. Structure of linear polyelectrolyte chains in dilute solution

10.2. Thermodynamics of polyelectrolyte solutions

10.3. Viscosity of polyelectrolyte solutions

Physical chemistry of macromolecules 1